Cyclisierungen unter beteiligung von fluoridionen, 3. Mittell. [1,2] teilfluorierte 1.3- und 1.4-dioxane |
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Authors: | Guenter Siegemund Warner Schwertfeger |
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Institution: | Hoechst Aktiengesellschaft Postfach 800320, D-6230 Frankfurt (Main) 80 B.R.D. |
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Abstract: | Cyclization of 2-(2-chloroethoxy)-perfluorocarboxylic acid halides 3 with alkali metal fluoride gives 2.3-perfluoro- 1.4-dioxanes 6 with yields up to 84 %. This reaction is also used for the preparation of 4.5.6-perfluoro-1.3- dioxanes 12 starting from 3-chloromethoxyperfluorocarbonyl compounds 11. — The preparation of starting materials is described. |
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