The thiolate anion as a nucleophile Part XI. Effect of the size of the nucleophile |
| |
Authors: | Thomas R. Crowell Michael E. Peach |
| |
Affiliation: | Chemistry Department, Acadia University, Wolfville, Nova Scotia, BOP 1XO Canada |
| |
Abstract: | The nucleophilic substitution reactions of some simple fluorobenzenes, C6H6?xFx with sodium methanethiolates Na+SR?(R=Et, -Pr, -Bu) have been studied. Some fully substituted products, C6H6?x(SR)x, could be obtained in DMF as solvent with R = Et and -Pr, but not when R = -Bu. All the new products isolated have been characterized by elemental analysis, and NMR (H-1 and F-19), infrared and mass spectroscopy. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|