Spontaneous reactions of xenon,flourine and antimony pentaflouride |
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| Authors: | L. Stein |
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| Affiliation: | Chemistry Division, Argonne National Laboratory, Argonne, Ill. 60439 U.S.A. |
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| Abstract: | Mixtures of xenon and fluorine gases react spontaneously with liquid antimony pentafluoride in the dark to form solutions of XeF+Sb2F?11. Dixenon cation, Xe+2, is formed as a labile intermediate product and is oxidized by the fluorine to XeF+ cation. The rate of the overall reaction is proportional to the partial pressure of xenon and the partial pressure of fluorine. This direct combination of reagents provides a simple method for the preparation of XeF+Sb2F?11. |
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