Preparative use of electrode catalyzed substitution reactions; synthesis of Fe(CO)(PPh3)(η5-C5H5)COCH3 |
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| Authors: | D. Miholová A.A. Vlček |
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| Affiliation: | The J. Heyrovský Institute of Physical Chemistry and Electrochemistry, Czechoslovak Academy of Sciences, Vla?ská 9, 118 40 Prague 1 Czechoslovakia |
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| Abstract: | It is shown that electrode catalysis of substitution reactions can operate even for systems with rather slow chemical steps and, furthermore, for those which are electrochemically irreversible. A procedure is described for synthesis of Fe(CO)(PPh3)(η5-C5H5)COCH3 from Fe(CO)2(η5-C5H5)CH3 and triphenylphosphine. A simplified mechanism for the catalytic chain, is given and discussed in terms of the structure of the reacting species. |
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