The reaction of uranium hexafluoride with silver fluoride in anhydrous hydrogen fluoride and the chemical properties of the product Ag2UF8 |
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| Authors: | John G. Malm |
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| Affiliation: | Chemistry Division, Argonne National Laboratory, Argonne, IL 60439 U.S.A. |
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| Abstract: | UF6 reacts with AgF dissolved in anhydrous hydrogen fluoride to precipitate Ag2UF8. Ag2UF8 has some unexpected properties: On reaction with water it produces O2 and reduced uranium. No adequate explanation could be found of why UF6 and AgF combined in this manner should produce a powerful oxidant. Raman spectra and chemical properties of the solid products are given. |
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