Polyfluorobicyclo[4,4,0]decanes. Part I. The fluorination of tetralin over cobalt trifluoride |
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| Authors: | Paul L Coe Ramzi M Habib John Colin Tatlow |
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| Institution: | Chemistry Department, The University of Birmingham, P.O. Box 363, Birmingham B15 2TT Great Britain. |
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| Abstract: | Fluorination of tetralin over cobalt trifluoride at 250° in a stirred reactor gave the known cis- and trans- perfluorodecalins and two known fluorobicyclo4,4,0]dec-1(6)-enes. Also obtained were five new heptadecafluorobicyclo4,4,0]decanes. Dehydrofluorinations of these gave five new hexadecafluorobicyclo4,4,0]decenes of which one, the 1(2)- isomer, rearranged readily to the 1(6)- isomer. |
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