The reaction of tetra(allyl)uranium with Lewis bases |
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| Authors: | Jan C. Vanderhooft Richard D. Ernst |
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| Affiliation: | Department of Chemistry, University of Utah, Salt Lake City, Utah 84112 U.S.A. |
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| Abstract: | The reaction of the thermally unstable U(π-C3H5)4 with an excess of 2,2′-bipyridine leads to incorporation of three 2,2′-bipyridine ligands in the thermally more stable product in which transfer of two of the four allyl groups to one or two of the 2,2′-bipyridine ligands has occurred. The product has been characterized analytically, spectroscopically, magnetically, and by detailed studies of hydrolysis products. |
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