Les tetraorganoetains optiquement actifs. Synthese et stereochimie dynamique sur l'atome de metal |
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| Authors: | M Lequan RM Lequan |
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| Institution: | Laboratoire de recherche de chimie organique, Ecole Nationale Supérieure de Chimie de Paris, 11, Rue Pierre et Marie Curie, 75231 Paris Cedex 05 France |
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| Abstract: | A general method of preparation of optically active organotin compounds by direct synthesis from R1R2R3SnX has been proposed. This method is based on attack of organometallic reagents on the tin atom attached to a chiral leaving group. Cinchonine and cinchonidine are the best inductors found. |
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