The crystal and molecular structure of tetraethylammonium hydrotris(3,5-dimethylpyrazolyl)boratotricarbonylmolybdenum(0), [NEt4][Mo(CO)3HB(C5H7N2)3] |
| |
Authors: | CP Marabella JH Enemark |
| |
Institution: | Department of Chemistry, University of Arizona, Tucson, Arizona 85721 U.S.A. |
| |
Abstract: | The crystal and molecular structure of tetraethylammonium hydrotris(3,5-dimethylpyrazolyl)boratotricarbonylmolybdenum(0), N(C2H5)4]Mo(CO)3? HB(3,5-Me2pz)3] has been determined from intensity data collected using counter methods. The salt crystallizes in space group Pna21 with parameters a = 18.038(6), b = 9.956(3), c = 16.881(3) Å, V = 3031.4(20) Å3, Z = 4, dcalc = 1.33 g/ml and dobs = 1.33 g/ml. Final convergence yielded a conventional R = 0.042 and a “goodness of fit” of 2.07. The steric pocket formed by the 3-methyl hydrogens of the pyrazolyl moiety is discussed. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|