TiCl(OCH3)(SO3Cl)(OSO2F)-chloro(chlorosulfato)(fluorosulfato)-methoxytitanium(IV) - asymmetric titanium(IV) compound |
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| Authors: | Michael Laska Ramesh C Kumar |
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| Institution: | Baldwin-Wallace College, Chemistry Department, Berea, Ohio 44017 U.S.A. |
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| Abstract: | A stable titanium(IV) compound with four different kinds of ligands, TiCl(OCH3)(SO3Cl)? (SO3F), results when TiCl2(OCH3)(SO3F) is refluxed with HSO3Cl using CH2Cl2 as the solvent. It is an off-white solid and decomposes around 125°C. The powder X-ray diffraction studies of the title compound will be discussed along with other physical and chemical properties. |
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