Indolylgold(I) derivatives and indole as π-arene ligands in cationic rhodium(I) complexes |
| |
| Authors: | Rafael Uson Luis A. Oro Javier A. Cabeza Mauricio Valderrama |
| |
| Affiliation: | Department of Inorganic Chemistry, University of Zaragoza, Zaragoza Spain;Department of Inorganic Chemistry, Institute of Chemical Sciences, Catholic University of Chile, Santiago Chile |
| |
| Abstract: | The reaction of LAuIn (L = P(C6H5)3, P(2-MeC6H4)3 or P(4-MeC6H4)3; In = indolyl group) with the solvated complexes [(diolefin)Rh(Me2CO)x]ClO4 gives the novel heterometallic complexes [(diolefin)Rh(μ-In)AuL]ClO4. The mononuclear arene derivatives [(diolefin)Rh(η6-HIn)]ClO4 react with methanolic KOH to give the binuclear complexes [(diolefin)Rh(μ-OMe)]2, while [(COD)Rh(η6-HIn)]ClO4 reacts with KOH in water/acetone to give the hydroxo-bridged complex [(COD)Rh(μ-OH)]2. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
