Novel transition metal phospha-alkyne complexes: tBuCP acting as a 6 electron donor ligand. Synthesis,crystal and molecular structure of [Co2(CO)6(μ-tBuCP)W(CO)5]期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Novel transition metal phospha-alkyne complexes: tBuCP acting as a 6 electron donor ligand. Synthesis,crystal and molecular structure of [Co2(CO)6(μ-tBuCP)W(CO)5]

Authors:	James CTR Burckett-St Laurent Peter B Hitchcock Harold W Kroto Mohammed F Meidine John F Nixon

Institution:	School of Chemistry and Molecular Sciences, University of Sussex, Brighton BN1 9QJ, Sussex Great Britain

Abstract:	A single crystal X-ray diffraction study of Co₂(CO)₆(μ-^tBuCP)W(CO)₅] establishes that phospha-alkyne behaves as a 6e donor. Synthesis of the related (η⁵-C₅H₅)₂Mo₂(CO)₄(μ-^tBuCP)W(CO)₅] complex is reported.

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