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The hydrolysis of dibromofluoromethyltriphenylphosphonium bromide |
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| Authors: | Donald J. Burton R.M. Flynn R.G. Manning R.M. Kessler |
| Affiliation: | Department of Chemistry, University of Iowa, Iowa City, Iowa 52242 U.S.A.;National Institutes of Health, Department of Nuclear Medicine, Bethesda, Maryland 20205 U.S.A. |
| Abstract: | Hydrolysis of [Ph3PCFBr2]Br? afforded a high yield of dibromofluoromethane and triphenylphosphine oxide. Hydrolysis in the presence of a radioactive isotope of bromine gave evidence that the mechanism of this reaction proceeds the dibromofluoromethide ion and not a bromofluorocarbene intermediate. |
| Keywords: | To whom correspondence should be addressed. |
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