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The hydrolysis of dibromofluoromethyltriphenylphosphonium bromide
Authors:Donald J. Burton  R.M. Flynn  R.G. Manning  R.M. Kessler
Affiliation:Department of Chemistry, University of Iowa, Iowa City, Iowa 52242 U.S.A.;National Institutes of Health, Department of Nuclear Medicine, Bethesda, Maryland 20205 U.S.A.
Abstract:Hydrolysis of [Ph3P+PCFBr2]Br? afforded a high yield of dibromofluoromethane and triphenylphosphine oxide. Hydrolysis in the presence of a radioactive isotope of bromine gave evidence that the mechanism of this reaction proceeds via the dibromofluoromethide ion and not via a bromofluorocarbene intermediate.
Keywords:To whom correspondence should be addressed.
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