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The hydrolysis of dibromofluoromethyltriphenylphosphonium bromide

Authors:	Donald J Burton RM Flynn RG Manning RM Kessler

Institution:	Department of Chemistry, University of Iowa, Iowa City, Iowa 52242 U.S.A.;National Institutes of Health, Department of Nuclear Medicine, Bethesda, Maryland 20205 U.S.A.

Abstract:	Hydrolysis of Ph₃ $P +$ PCFBr₂]Br^? afforded a high yield of dibromofluoromethane and triphenylphosphine oxide. Hydrolysis in the presence of a radioactive isotope of bromine gave evidence that the mechanism of this reaction proceeds $via$ the dibromofluoromethide ion and not $via$ a bromofluorocarbene intermediate.

Keywords:	To whom correspondence should be addressed
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