| Preparation and Crystal Structure of Hetero—metal Clusters[η^5—C5H4C（O）CH2CH2C（O）OCH3]FeCoM（μ3—S）（CO）8（M=Mo or W） |
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| 引用本文： | 张玉华,袁建超,等.Preparation and Crystal Structure of Hetero—metal Clusters[η^5—C5H4C（O）CH2CH2C（O）OCH3]FeCoM（μ3—S）（CO）8（M=Mo or W）[J].结构化学,2001,20(5):363-368. |
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| 作者姓名： | 张玉华 袁建超 等 |
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| 作者单位： | State Key Laboratory for Oxo Synthesis and Selective Oxidation，Lanzhou Institute of Chemical Physics，Chinese Academy of Sciences，Lanzhou，730000. Email: hcom@ns.lzb.ac.cn |
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| 基金项目： | the National Natural Science Foundation of China. |
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| 摘 要： | 1 INTRODUCTIONTransition metal clusters have been attracting intensive attention largely because they are suggested as active catalysts in a variety of homogeneous catalyzed reactions. However, no unequivocal proof exists that metal clusters themselves serve as the true catalysts among the catalytic process. In many cases it is known that fragments of the original clusters are the actual catalytic species. The unambiguous proof would be the use of a rigid chiral cluster to catalyze an asy…
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| 关 键 词： | [η^5－C5H4C（O）CH2CH2C（O）OCH3]FeCoM（μ3－S）（CO）8 铁 钼 簇合物 晶体结构 |
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