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| Synthesis and Crystal Structure of [(NH_4)_6][Gd_2Mo_(36)O_(112)(H_2O)_(20)]·52H_2O | |
| 作者姓名： | WU Chuan-De LIN Xiang YANG Wen-Bin LU Can-Zhong② ZHUANG Hong-Hui ( State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 350002 P. R. China) |
| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，P. R. China |
| 基金项目： | the State Education Ministry, the State Personal Ministry, National Natural Science Foundation of China (20073048) and the Chine |
| 摘 要： | 1 INTRODUCTION There is considerable interest in the heteropolymetalates in view of their potential applications in many fields, such as, catalysis, biology, medicine, magnetochemistry, and materials science[1～5]. It has been well- known that the rare earth elements are highly oxophilic and the anion of polyoxomolybdates have oxygen-rich composition, which can be used as synthons for the construction of novel heteropolymetalates. Since the structure of polyoxoanion 36-molybdate Mo36O1128… |
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