| Synthesis and Crystal Structure of 18-Tungstotetranickel(II) diphosphate Na_(10){(PW_9O_(34))_2Ni_4(H_2O)_2}·26H_2O |
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| 作者姓名： | CUI Chuan-Peng DAI Jing-Cao DU Wen-Xin WU Li-Ming FU Zhi-Yong HU Sheng-Min WU Xin-Tao② (State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 350002 Chi |
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| 作者单位： | State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,Chi |
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| 基金项目： | grants from the State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, the |
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| 摘 要： | 1 INTRODUCTIONThe inorganic chemistry concentrating on polyoxometallates, is in a position to connect elementary building blocks and their derivatives in different ways, enabling people to synthesize a large variety of remarkable substances, especially those in the "nanoworld". Of particular importance is the anionic-type which has {MOx}-type building-block units, where M stands for the d block elements in high oxidation states.[1] In 1973 Weakley, Evans and Showell isolated[2] K10P2W1…
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