Synthesis, structure and magnetic behavior of a new three-dimensional Manganese phosphite-oxalate: [C2N2H10][Mn2(OH2)2(HPO3)2(C2O4)] |
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| Authors: | Padmini Ramaswamy Sukhendu Mandal Srinivasan Natarajan |
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| Institution: | aFramework Solids Laboratory, Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012, India |
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| Abstract: | A novel manganese phosphite-oxalate, C2N2H10]Mn2II(OH2)2(HPO3)2(C2O4)] has been hydothermally synthesized and its structure determined by single-crystal X-ray diffraction. The structure consists of neutral manganese phosphite layers, Mn(HPO3)]∞, formed by MnO6 octahedra and HPO3 units, cross-linked by the oxalate moieties. The organic cations occupy the middle of the 8-membered one-dimensional channels. Magnetic studies indicate weak antiferromagnetic interactions between the Mn2+ ions. |
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| Keywords: | Template synthesis X-ray diffraction Hybrid compounds Manganese Phosphite |
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