Chiral counteranion-aided asymmetric hydrogenation of acyclic imines |
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| Authors: | Li Chaoqun Wang Chao Villa-Marcos Barbara Xiao Jianliang |
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| Affiliation: | Department of Chemistry, Liverpool Centre for Materials and Catalysis, University of Liverpool, Liverpool L69 7ZD, UK. |
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| Abstract: | When combined with a chiral phosphate counteranion, a chiral diamine-ligated Ir(III) catalyst displayed excellent enantioselectivities in the asymmetric hydrogenation of a wide range of acyclic imines, affording chiral amines in up to 99% ee. |
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