A non-Diels-Alder approach to the cis-decalin core of branimycin |
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| Authors: | Enev Valentin S Drescher Martina Mulzer Johann |
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| Institution: | Institut für Organische Chemie, W?hringerstrasse 38, A-1090 Wien, Austria. valentin.enev@univie.ac.at |
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| Abstract: | The synthesis of the highly substituted cis-decalin core of branimycin has been accomplished. A catalytic copper mediated SN2' opening of oxabicycle 7 with Grignard reagent and ring-closing metathesis served as key transformations. |
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