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聚乙二醇包裹羰基铁核壳粒子的制备及水基磁流变液的性能
引用本文:李立春,官建国,程海斌,陶剑青. 聚乙二醇包裹羰基铁核壳粒子的制备及水基磁流变液的性能[J]. 物理化学学报, 2005, 21(7): 817-821. DOI: 10.3866/PKU.WHXB20050724
作者姓名:李立春  官建国  程海斌  陶剑青
作者单位:State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070
基金项目:国家高技术研究发展规划(863)项目(2001AA339020)资助项目~~
摘    要:以羰基铁粉(CI)为原料用共溶胶-凝胶反应制备CI/聚乙二醇核壳复合粒子,并将其与水组成了磁流变液. 用SEM、TEM、FT-IR和VSM表征了核壳复合粒子的微观结构和静磁特性,并测试了水基磁流变液的性能. 结果表明,核壳复合粒子表面有SiOx和聚乙二醇的包覆层,它有较好的亲水性和优良的软磁特性,用它组成的水基磁流变液具有抗沉降性优良、零场粘度低、磁流变效应显著等特点.

关 键 词:水基磁流变液  羰基铁粉  溶胶-凝胶  核壳粒子  
收稿时间:2004-11-16
修稿时间:2004-11-16

Preparation of Poly(ethylene glycol)-coated Carbonyl Iron Particles for Aqueous Magnetorheological Suspension
Li Li-chun,GUAN Jian-Guo,CHENG Hai-bin,TAO Jian-qing. Preparation of Poly(ethylene glycol)-coated Carbonyl Iron Particles for Aqueous Magnetorheological Suspension[J]. Acta Physico-Chimica Sinica, 2005, 21(7): 817-821. DOI: 10.3866/PKU.WHXB20050724
Authors:Li Li-chun  GUAN Jian-Guo  CHENG Hai-bin  TAO Jian-qing
Affiliation:State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070
Abstract:A novel magnetorheological (MR) suspension is based on the mixture of poly(ethylene glycol)-coated carbonyl iron particles, prepared by the co-sol-gel reaction using carbonyl iron particles as raw materials, and water without any additive. The microstructure, magnetic and magnetorheological properties of the core-shell particles are characterized by SEM、TEM、FT-IR、VSM. The results show that the particles prepared have core-shell structure with a polymer shell of less than 100 nm; both the core-shell particles and its water based MR suspension exhibit excellent soft magnetic performance; the water based MR suspension shows low zero viscosity and high MR effects, especially greatly improved anti-settlement and redispersibility. The phenomena are attributed to the hydrophilic thin shell of the core-shell particles.
Keywords:Water-based magnetorheological fluid  Carbonyl iron powder  Sol-gel  Core shell particle  
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