Synthetically tailored excited states: phosphorescent, cyclometalated iridium(III) complexes and their applications |
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Authors: | Lowry Michael S Bernhard Stefan |
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Institution: | Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA. |
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Abstract: | Phosphorescent iridium(III) complexes are being widely explored for their utility in diverse photophysical applications. The performance of these materials in such roles depends heavily on their excited-state properties, which can be tuned through ligand and substituent effects. This concept article focuses on methods for synthetically tailoring the properties of bis-cyclometalated iridium(III) materials, and explores the factors governing the nature of their lowest excited state. |
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Keywords: | iridium luminescence OLEDs photochemistry structure–property relationships |
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