| 磷酸锗铁铝分子筛的合成与鉴定 |
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| 引用本文： | 韩淑芸,王立群.磷酸锗铁铝分子筛的合成与鉴定[J].高等学校化学学报,1990,11(11):1171-1174. |
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| 作者姓名： | 韩淑芸 王立群 |
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| 作者单位： | 青岛大学化学系，吉林大学化学系，吉林大学化学系 266071 |
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| 摘 要： | 在氟离子体系中,合成了磷酸锗铁铝分子筛GeFeAPO-5的纯相,吸附吡啶后的红外光谱表明GeFeAPO-5分子筛中存在Brnsted酸和Lewis酸中心;X射线衍射分析、晶胞参数测定、电子探针、红外光谱、穆斯堡尔谱、电子顺磁共振谱、固体高分辨魔角旋转核磁共振谱等结果表明,锗和铁进入了GeFeAPO-5分子筛骨架。
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| 关 键 词： | 分子筛 合成 鉴定 磷酸锗铁铝 |
Synthesis and Identification of GeFeAPO-5 Molecular Sieve |
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| Han Shuyun.Synthesis and Identification of GeFeAPO-5 Molecular Sieve[J].Chemical Research In Chinese Universities,1990,11(11):1171-1174. |
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| Authors: | Han Shuyun |
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| Abstract: | GeFeAPO-5 molecular sieve was synthesized in the system of fluoride ions. After adsorption of pyridine the IR spectra showed the presence of both Bronsted and Lewis acid sites. GeFeAPO-5 molecular sieve was identified by means of X-ray diffraction analysis, determination of the unit cell parameters, electron probe, infrared spectra, Mossbauer spectroscopy, electron paramagnetic resonance spectrum, high resolution magic-angle-spinning solid state 31P and 27A1 nuclear magnetic resonance. The results showed Fe and Ge entered into the GeFeAPO-5 framework. |
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| Keywords: | Molecular sieve Aluminophosphate Germanium Iron |
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