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Synthesis and Structure of K_3Na_3〔MnMo_9O_(32)〕·6H_2O
作者姓名:YANG Xi--Ping   SHAO Shi--Bao   CHEN Chang-Zhang   HUANG Xiao--Ying   LIN Zhou--Bin   Gao Dong--Shou (Fujian Institute of Research on the Structure of Matter  the Chinese Academy of Sciences  Fuzhou  350002)
作者单位:Fujian Institute of Research on the Structure of Matter,the Chinese Academy of Sciences,Fuzhou,350002
摘    要:1INTRODUCTIONHeteroPOlymolybdatesareknownwithaverywiderangeofmetalionsithetypeandstabilityoftheclustersshowdependenceonboththeheteroatomandPH"'.TheknownheteroPOlymolybdateswhichincludemanganese(1)ormanganese(IV)havebeenreported.Afewofhetercrg-molybdateanionswiththemanganese(IIV)andnickel(IV)formsarecharacterizedandisostructural[2).Thesehigheroxidationstatespecieshavebeenpreparedpreviouslybyoxidationoflower--valentspecieswithPOwerfuloxidant,suchasPeroxydisulfateorPeroxymonosulfurica…

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