Synthese und Kristallstruktur von BaVo2,5 |
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Authors: | Dieter Chales de Beaulieu Hanskarl Müller-Buschbaum |
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Institution: | (1) Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, D-2300 Kiel, Bundesrepublik Deutschland |
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Abstract: | Single crystals of BaVO2,5 were prepared by high temperature LASER-technique under a hydrogen atmosphere. The X-ray investigation leads to a trigonal symmetry (a=571.8;c=1161.3 pm, space group C
3v
1
-P3m 1). BaVO2,5 consists of a closest sphere packing of oxygen with a sequence of cubic and hexagonal layers of the type ... ccchh ... The consequences in respect to the coordination of Ba2+ and V3+ are discussed. |
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Keywords: | Barium Oxygen Single crystal Vanadium X-ray |
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