Structure of bis(dipropyldithiocarbamate) cadmium(II), [Cd2(n-Pr2dtc)4] (dtc = dithiocarbamate) |
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Authors: | Fangfang Jian Zuoxiang Wang Zhiping Bai Xiaozeng You Hoong-Kun Fun Kandasamy Chinnakali |
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Affiliation: | (1) Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P. R. China;(2) X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia |
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Abstract: | The cadmium complex of bis(dipropyldithiocarbamate), [Cd2(n-Pr2dtc)4] (dtc = dithiocarbamate) was crystallized from ethylether. It crystallizes in the monoclinic system, space group P2I/c, with lattice parameters, a = 8.2532(1), b = 19.4519(1), c = 13.4163(2) Å, = 99.243(1)°, and Z = 4. The X-ray single-crystal structure of [Cd2(n-Pr2dtc)4] reveals that the complex is binuclear in the solid state and the Cd atom has a distorted square-pyramidal coordination environment and four equatorial donors are the two bidentate chelate sulfur atoms from two dtc ligands, of which the sulfur atom from the bridging dtc ligand occupies the apical position of the symmetry-related Cd atom in the dimer structure. |
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Keywords: | X-ray structure dtc cadmium complex |
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