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Physical properties of high-nuclearity metal cluster compounds |
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| Authors: | L J de Jongh J Albino O de Aguiar H B Brom G Longoni J M van Ruitenbeek G Schmid H H A Smit M P J van Staveren R C Thiel |
| Institution: | 1. Kamerlingh Onnes Laboratorium, Rijksuniversiteit Leiden, Postbus 9506, NL-2300 RA, Leiden, The Netherlands 3. Dipartimento di Chimica Fisica ed Inorganica, Viale del Risorgimento, 4 40136, Bologna, Italia 4. Institut für Anorganische Chemie, Universit?t Essen, Universit?tsstrasse, S-7, D-4300, Essen, Federal Republic of Germany |
| Abstract: | Metal cluster compounds are composed of large macromolecules, which consist of a metal core (cluster) containing a certain number (n=6–560) of metal atoms, to which core a shell of ligands is coordinated. They provide excellent model systems for an assembly of identical metal clusters, embedded in a dielectric matrix. We discuss a number of physical properties of these materials. |
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