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Sodium clusters in zeolites
Authors:P. J. Grobet  L. R. M. Martens  W. J. M. Vermeiren  D. R. C. Huybrechts  P. A. Jacobs
Affiliation:1. Laboratorium voor Oppervlaktechemie, K.U. Leuven, Kardinaal Mercierlaan 92, B-3030, Leuven, Belgium
Abstract:The method of loading sodium clusters in zeolites, consisting of the controlled thermal decomposition of physisorbed sodium azide, is discussed. The influence of the azide loading, the azide decomposition rate and the sintering process on the amount of ionic and metallic sodium clusters in zeolite Y was followed by ESR. The method is compared to other metal deposition techniques.
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