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A New Condensation Reaction of β-Keto-δ-valerolactone with Substituted Aniline
作者姓名:You Ming WANG   Jia Feng LI   Zheng Ming LI(State Key Laboratory of Elemento-Organic Chemistry. Nankai University. Tianjin 300071)
摘    要:Pyronesareimportantintermediatesofpesticidesandpharmaceuticals'.Recentlythebiologicalactivitiesofpyronederivativeshavedrawngreatinterest,butfewliteraturesonthebiologicalactivitiesof0-keto-8-valerolactonederivativeswerereported.The3positionof0-keto-5-valerolactonesisparticularlyreactive,acylationcantakeplaceinthisposition'-'.Herewereportanewcondensationreactionof6-keto-5-valerolactone,bymeansofwhichnewcarbon-carbondoublebondwasformedandaserisofnewanilinomethylenecompoundswereobtained.Synthesiso…

关 键 词:Condensation reaction   β-keto-δ-valerolactone   intramolecular hydrogen bond
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