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A chemical oscillating reaction in NaBrO3-pyruvic acid-H2SP4--[Ni(Me2[14]1,3-diene N4)]2+ system
Authors:Liang Zhao  Zhi-Qiang Xu  Chang-Chun Wu  Fu-Xin Xie  Shi-Sheng Ni  Yi Luo
Abstract:In this paper we report a chemical oscillation catalyzed by Ni(Me214]l,3-diene N4)]2+ (Me214]1,3-diene N4 denotes 2,3-dimethyl-1,4,8,11-tetraazacyclotetradeca-1,3-diene) in BrO3-pyruvic acid-H2SO4 system. The domain of the existence of the oscillation waa obtained. The effect of initial concentration of the components on the oscillation were studied. The features of the oscillations were described in detail. We also examined the effects of Ag+, Hg2+, CCl4, free radical inhibitors, etc. on the oscillations.
Keywords:Chemical oscillation  catalysis  initial concentration
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