离子液体表/界面性质与结构

离子液体与气体、溶剂等物质组成的多相体系为吸收、萃取、两相催化等技术的发展提供了新的平台。离子液体的表/界面性质与结构是含离子液体多相体系的重要科学问题,可在介观尺度下显著影响多相体系反应和分离过程的效率。近年来,离子液体表/界面性质和结构的研究得到了广泛的关注。本文综述了离子液体及其与水、有机溶剂组成的混合物的表/界面张力及结构研究进展,介绍了现有的研究方法、研究对象与研究成果,归纳了离子液体及其混合物表/界面张力及结构的变化规律,分析了表/界面结构与表/界面张力之间的关系,探讨了离子液体表/界面研究存在的问题和未来的发展方向。

Surface/Interfacial Properties and Structures of Ionic Liquids

Heterogeneous systems containing ionic liquids(ILs) with gases and solvents extend the acpplications of ILs in absorption,extraction and heterogeneous catalysis.In recent years,the surface/interfacial properties and surface/interfacial structures of ionic liquids have been widely studied,because they are important due to their remarkable effects on heterogeneous reactions and separation efficiency.In this article,the surface/interfacial tension,as well as the surface/interfacial structures of ILs and their mixtures with water and organic solvents are summarized.The research methods,objectives and results are introduced.The relationship between surface/interfacial tension and surface/interfacial structures is elucidated.Finally,the exiting problems and development prospects of the studies on surface/interfacial properties and surface/interfacial structures of ILs are discussed.