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Thermochemicalstudies on the thioproline
Authors:L. Qiang-Guo  L. Xu  D. Bin  Y. Xu-Wu
Affiliation:(1) College of Chemistry and Life Science, Xiangnan University, Chenzhou, Hunan, China, 423000;(2) Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xi ’an, Shaanxi, China, 710069
Abstract:The combustion energy of thioproline was determined by the precision rotating-bomb calorimeter at 298.15 K to be Δc U= –2469.30±1.44 kJ mol–1. From the results and other auxiliary quantities, the standard molar enthalpy of combustion and the standard molar enthalpy of formation of thioproline were calculated to be Δc H m θC4H7NO2S, (s), 298.15 K= –2469.92±1.44 kJ mol–1 and Δf H m θC4H7NO2S, (s), 298.15K= –401.33±1.54 kJ mol–1.
Keywords:combustion energy  rotating-bomb calorimeter  standard enthalpy of formation  thioproline
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