Analysis of electrocatalytic reaction schemes: distinction between rate-determining and potential-determining steps |
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| Authors: | Marc T M Koper |
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| Institution: | 1. Leiden Institute of Chemistry, Leiden University, PO Box 9502, 2300 RA, Leiden, The Netherlands
2. Catalysis Research Center, Hokkaido University, Sapporo, 001-0021, Japan
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| Abstract: | This paper discusses the concepts of rate-determining step and potential-determining step in the context of electrocatalytic reaction schemes, illustrates how the simpler concept of potential-determining step often captures the essence of a bottleneck in a reaction scheme, and thereby provides straightforward hints for developing better catalysts. |
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