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Some novel efforts to describe the nucleation and growth at electrodeposition
Authors:Yu Gamburg
Institution:1. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Leninski prospekt, 119071, Moscow, Russia
Abstract:Some alternative ways are developed of looking at the model concepts on electrochemical nucleation. The article consists in several parts concerning several stages of the overall process of nucleation and growth: the statistical approach to nucleation kinetics, the kinetics of the initial stage of the nuclei growth, the growth of an individual cluster under combined charge transfer and diffusion control, nucleation rate and the overall number of clusters, the growth of an increasing number of clusters at overlapping of diffusionally depleted zones, and galvanostatic nucleation.
Keywords:
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