Suppression of aggregation-induced fluorescence quenching in pyrene derivatives: photophysical properties and crystal structures |
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Authors: | Zuo-Qin LiangYe-Xin Li Jia-Xiang YangYan Ren Xu-Tang Tao |
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Affiliation: | a State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, PR China b Department of Chemistry, Anhui University, Hefei 230039, PR China |
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Abstract: | Two new pyrene-based fluorophores, namely 1-[4-(2,2-diphenylvinyl)phenyl]pyrene (PVPP) and 1,3,6,8-tetrakis[4-(2,2-diphenylvinyl)phenyl]pyrene (TPVPP), were synthesized through Suzuki coupling reaction and well characterized. PVPP successfully suppresses the fluorescence quenching of pyrene units in the solid state, displaying aggregation-induced enhanced emission. Despite the same substituent, TPVPP shows a different fluorescent behavior. On the basis of the crystal structures, the distinct optical behavior is discussed and clarified. The intermolecular C-H?π interaction has a dramatic effect on their photophysical properties in the solid state. |
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Keywords: | Pyrene Fluorescence quenching Aggregation-induced enhanced emission Crystal structure |
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