Palladium catalyzed N-alkylation of amines with alcohols |
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| Authors: | Yan ZhangXiujuan Qi Xinjiang Cui Feng Shi Youquan Deng |
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| Institution: | a Centre for Green Chemistry and Catalysis, Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000, China
b Graduate School of Chinese Academy and Science, Beijing 100049, China |
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| Abstract: | An iron oxide immobilized palladium catalyst was prepared for the N-alkylation of amines with alcohols under base and organic ligand free conditions. Applying the optimized reaction conditions, the coupling reactions of amines and alcohols with various structures could be realized with up to 99% isolated yields. The catalysts were studied by XRD, BET, and XPS and the mechanism was studied by DFT calculations. |
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| Keywords: | Palladium Alkylation Alcohol Amine |
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