Influence ofE/Z isomerism of aldoximes on the direction of their alkylation with oxirane |
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| Authors: | S M Bakunova I A Grigor'ev L B Volodarsky |
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| Institution: | 1. Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Acad. Lavrent'eva, 630090, Novosibirsk, Russian Federation
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| Abstract: | The reaction ofZ-2-furaldoxime with oxirane afforded theN-alkylation product,viz., α-2-furyl-N-(2-hydroxyethyl)nitron, in good yield.E-Benzaldoxime gave predominantly theO-alkylation product, while itsZ isomer was converted into a mixture with theN-alkylation product slightly predominating. |
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