The chemistry of naphthazarin derivatives |
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Authors: | A. Ya. Chizhova T. Yu. Kochergina V. F. Anufriev V. A. Denisenko V. P. Glazunov |
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Affiliation: | (1) Pacific Institute of Bioorganic Chemistry, Far-East Branch, Russian Academy of Sciences, Russian Federation, 690022, Vladivostok, prosp, 100-Letiya Vladivostoka, 159, Russia;(2) Institute of Chemistry and Applied Ecology, Far-East State University, Russian Federation, 690600, Vladivostok, ul. Oktyabr’skaya, 27, Russia |
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Abstract: | The 7,7′-dideoxy analog of islandoquinone, binaphthazarin of a new structural type, bearing a 2-oxo-2,3-dihydro-1,4-naphthoquinone moiety was synthesized. The carbonyl group at the C(2) atom of this binaphthazarin easily adds water to give the correspondinggem-diol. Comparison of the spectral characteristics of the prepared diol and islandoquinone made it possible to elucidate more precisely the structure of the latter. |
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