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Nature of the first exothermic peak on the DSC curve of linear polydicyclopentadiene obtained with a special catalytic system |
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| Authors: | Doina Dimonie M Dimonie V Munteanu H Iovu J Couve M J Abadie |
| Institution: | a ICECHIM, Chemical Research Institute, Splaiul Independentei Nr 202, 77208 Bucharest 6, Romania b “Politehnica” University, Polizu 1 Bucharest, Romania c NISREE, Spl.Unirii, No.313, Bucharest, Romania d University Montpellier II, Montpellier, France |
| Abstract: | A DSC and TGA study of linear polydicyclopentadiene (L-PDCPD) shows that the thermal behaviour of this polymer is characterized by an endothermic and two exothermic processes. In previous work it was demonstrated that the endothermic process is a glass transition and the second exotherm represents the thermo-oxidation of the polymer. In this work the first exothermic process is shown to be a possible thermal polymerization of the double bonds in the polymer chains. |
| Keywords: | Linear polydicyclopentadiene Thermal polymerization Thermo-oxidation Crosslinking Polyannelated structure FTIR simulation |
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