| 卤键在超分子化学中的应用进展 |
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| 引用本文： | 王友兵,石淑先.卤键在超分子化学中的应用进展[J].化学通报,2012(2):106-113. |
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| 作者姓名： | 王友兵 石淑先 |
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| 作者单位： | 白城医学高等专科学校;北京化工大学材料科学与工程学院碳纤维及功能高分子教育部重点实验室 |
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| 基金项目： | 国家高技术研究发展计划(“863计划”)项目(2009AA032802)资助 |
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| 摘 要： | 卤键是指作用在卤原子(路易斯酸)和具有孤对电子的原子或π电子体系(路易斯碱)之间的新型弱相互作用,其在超分子多维自组装和分子识别(如超分子催化、超分子选择拆分、超分子传感)等领域有着广泛的应用。本文介绍了卤键的类别、特性、功能及在超分子化学结构与功能领域中的应用。
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| 关 键 词： | 卤键 超分子化学 应用 |
Development on Application of Halogen Bond in Supramolecular Chemistry |
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| Wang Youbing,Shi Shuxian.Development on Application of Halogen Bond in Supramolecular Chemistry[J].Chemistry,2012(2):106-113. |
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| Authors: | Wang Youbing Shi Shuxian |
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| Institution: | 1Baicheng Medical College,Baicheng 137000;2Key Laboratory of Carbon Fiber and Functional Polymers,Ministry of Education,Beijing University of Chemical Technology,Beijing 100029) |
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| Abstract: | Halogen bond is defined as a new type of weak interaction between halogen atoms(Lewis acid) and objects with lone-pairs or π-electron systems(Lewis base).It plays an important role in multi-dimensional supramolecular self-assembly,supramolecular recognition,such as supramolecular catalysis,supramolecular chiral resolution,supramolecular sensing and transmission,and some other fields.The properties of halogen bond,such as type,characteristics and functions,as well as applications in supramolecular chemistry were introduced. |
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| Keywords: | Halogen bond Supramolecular chemistry |
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