Mn(bipyridyl)(CO)(3) Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO(2) Reduction |
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| Authors: | Bourrez Marc Molton Florian Chardon-Noblat Sylvie Deronzier Alain |
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| Affiliation: | Université Joseph Fourier-Grenoble1/CNRS, Département de Chimie Moléculaire UMR 5250, Laboratoire de Chimie Inorganique Redox, Institut de Chimie Moléculaire de Grenoble FR-CNRS-2607, BP53, 38041 Grenoble cedex 09 (France). |
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| Abstract: | Manganese at work: Carbonyl bipyridyl complexes based on manganese, a non-noble abundant and inexpensive metal, have been proved to be excellent molecular catalysts for the selective electrochemical reduction of CO(2) to CO under mild conditions. Another advantage of manganese complexes over rhenium complexes is that these catalysts operate at markedly less overpotential (0.40?V gain). |
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| Keywords: | carbon dioxide carbonyl ligands electrocatalysis electrochemistry manganese |
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