Model for infrared and Raman studies of molecular rotations in liquids and gases |
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Authors: | S Dattagupta A K Sood |
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Institution: | (1) Reactor Research Centre, 603 102 Kalpakkam |
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Abstract: | Experimental infrared and Raman data for molecular rotations in dense phases often lie in between the results predicted by
theJ- andM-diffusion models of Gordon. In this paper, we present a theory which is similar in its basic approach to Gordon’s extended
diffusion models (EDM) but in which the restrictions of theJ andM limits are removed. The outcome is a scheme which allows one to describe situations which fall between the two extreme pictures
of theJ andM models. Application of this scheme to experiments is discussed. |
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Keywords: | Molecular rotations infrared line shapes Raman line shapes generalised extended diffusion models |
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