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Benzothiazolium-functionalized tetraphenylethene: an AIE luminogen with tunable solid-state emission
Authors:Na Zhao  Zhiyong Yang  Jacky W Y Lam  Herman H Y Sung  Ni Xie  Sijie Chen  Huimin Su  Meng Gao  Ian D Williams  Kam Sing Wong  Ben Zhong Tang
Institution:Department of Chemistry, Institute for Advanced Study, State Key Laboratory of Molecular Neuroscience, Institute of Molecular Functional Materials and Division of Biomedical Engineering, The Hong Kong University of Science & Technology (HKUST), Clear Water Bay, Kowloon, Hong Kong, China. tangbenz@ust.hk.
Abstract:Melding a benzothiazolium unit with tetraphenylethene generates a new hemicyanine luminogen with aggregation-induced emission characteristics; the luminogen exhibits crystochromism and its solid-state emission can be repeatedly tuned from yellow or orange to red by grinding-fuming or grinding-heating processes due to the transformation from the crystalline to the amorphous state and vice versa.
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