Ge(9) {Si(SiMe(3) )(3) }(3) {SnPh(3) }]: A Tetrasubstituted and Neutral Deltahedral Nine-Atom Cluster |
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Authors: | Feng Li Alvaro Muñoz-Castro Slavi C Sevov |
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Institution: | Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556 (USA) http://www.nd.edu/~ssevov. |
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Abstract: | Reaching neutral territory: The title compound, the first tetrasubstituted deltahedral Zintl cluster, is no longer an ion (see picture; Ge?green, Si?purple, Sn?blue). It is a neutral molecule formed by a reaction of the trisilylated anion with Ph(3) SnCl. |
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Keywords: | clusters germanium structure elucidation Zintl anions |
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