| SYNTHESES OF POLYMER-BOUND RHODIUM COMPLEXES AND THEIR APPLICATION AS CATALYSTS FOR THE HYDROFORMYLATION OF DIISOBUTYLENE (Ⅱ) |
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| 引用本文： | 何炳林,孙君坦,李弘,郑凤萍,蔡慧青,周启昭,杨旭清,刘光宏,刘德弘,王小华.SYNTHESES OF POLYMER-BOUND RHODIUM COMPLEXES AND THEIR APPLICATION AS CATALYSTS FOR THE HYDROFORMYLATION OF DIISOBUTYLENE (Ⅱ)[J].中国科学B辑(英文版),1987(1). |
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| 作者姓名： | 何炳林 孙君坦 李弘 郑凤萍 蔡慧青 周启昭 杨旭清 刘光宏 刘德弘 王小华 |
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| 作者单位： | Institute of Polymer Chemistry，Nankai University，Institute of Polymer Chemistry，Nankai University，Institute of Polymer Chemistry，Nankai University，Institute of Polymer Chemistry，Nankai University，Institute of Polymer Chemistry，Nankai University，Beijing Research Institute of Chemical Industry，Beijing Research Institute of Chemical Industry，Beijing Research Institute of Chemical Industry，Beijing Research Institute of Chemical Industry，Beijing Research Institute of Chemical Industry |
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| 基金项目： | Fu Chuangui, Wang Yuqin, Weng Junfan and Pang Jianmin participated in part of the research work，The project was supported by the Science Fund of the Chinese Academy of Sciences. |
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| 摘 要： | Five kinds of polymer-anchored aminophosphine-rhodium complexes were synthesizedby ionic and covalent bonding methods. These anehored rhodium complexes synthesizedpossess good catalytic activity and aldehyde-formation selectivity in the hydroformylationof diisobutylene. The complexes anchored via covalent bonds on polymers showedexcellent reproducibility on recycling. After reaction, it indicated that the loss of rhodiumof the catalysts was very small as shown by analysis.
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