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Radical telomerization of 1-hexene with butyraldehyde
Authors:S A Orlova  A B Terent'ev
Institution:1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow
Abstract:
1.  Telomerization of 1-hexene with butyraldehyde results in the formation of two main series of telomers — ketones and hydrocarbons.
2.  In the reaction studied, radical rearrangement with 1,6-migration of a hydrogen atom along the chain containing a carbonyl group occurs to a significant extent.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 874–878, April, 1989.
Keywords:
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