Multielectron reduction of diazoalkane and azides via reversible cyclometalation in ditantalum complexes |
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| Authors: | Kurogi Takashi Ishida Yutaka Hatanaka Tsubasa Kawaguchi Hiroyuki |
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| Affiliation: | Department of Chemistry, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8551, Japan. |
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| Abstract: | Reactions of the cyclometalated hydride complexes with diazo and azide substrates are reported. While diazoalkane undergoes four-electron N-N bond cleavage, azides undergo two-electron N(2) extrusion. |
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