In situ synthesis of nickel tiara-like clusters with two different thiolate bridges |
| |
| Authors: | Tan Chunhong Jin Meiliang Ma Xiao Zhu Qilong Huang Yihui Wang Yanlong Hu Shengmin Sheng Tianlu Wu Xintao |
| |
| Institution: | State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China. |
| |
| Abstract: | Four nickel clusters, cyclo-{Ni(μ-S(i)Pr)(μ-SMe)}(6)] (1), cyclo-{Ni(μ-StBu)(μ-SMe)}(6)] (2), cyclo-{Ni(μ-S(i)Pr)(μ-SEt)}(6)] (3) and cyclo-{Ni(μ-StBu)(μ-SEt)}(10)] (4), based on thiolate ligands have been successfully synthesized and characterized by elemental analysis, FT-IR spectra, UV-vis-NIR spectra, powder X-ray diffraction and single-crystal X-ray diffraction. Intriguingly, the SMe and SEt ligands are generated from solvothermal in situ ligand synthesis through the cleavage of the S-S bond respectively. The four nickel thiolate clusters exhibit tiara-like frameworks consisting of two different types of thiolate ligands. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
