Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour |
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| Authors: | Gaillard Sylvain Rix Diane Slawin Alexandra M Z Lacour Jérôme Nolan Steven P |
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| Institution: | EaStCHEM School of Chemistry, University of St Andrews, St Andrews, KY16 9ST, UK. |
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| Abstract: | The synthesis and characterization of a new class of cationic (NHC)gold(I) (NHC = N-Heterocyclic carbene) complex containing the phosphate counterions TRISPHAT and TRISPHAT-N have been achieved. The selection of the appropriate hexacoordinated phosphate architecture permits the isolation of complexes bearing an inner or outer sphere anionic counterion. |
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