Nitrogen doped tin oxide nanostructured catalysts for selective electrochemical reduction of carbon dioxide to formate |
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Institution: | 1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, 29 Zhongguancun East Road, Haidian District, Beijing 100190, China;2. University of Chinese Academy of Sciences, 19A Yuquan Road, Beijing 100049, China |
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Abstract: | Tin/tin oxide materials are key electrocatalysts for selective conversion of CO_2 to formate/formic acid.Herein we report a tin oxide material with nitrogen doping by using ammonia treatment at elevated temperature. The N doped material demonstrated enhanced electrocatalytic CO_2 reduction activity, showing high Faradaic efficiency(90%) for formate at -0.65 V vs. RHE with partial current density of 4 mA/cm~2.The catalysis was contributed to increased electron negativity of N atom compared to O atom. Additionally, the N-doped catalyst demonstrates sulfur tolerance with retained formate selectivity. The analysis after electrolysis shows that the catalyst structure partially converts to metallic Sn, and thus the combined Sn/N-SnO_2 is the key for the active CO_2 catalysis. |
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